Article ID Journal Published Year Pages File Type
5276032 Tetrahedron Letters 2011 4 Pages PDF
Abstract

The dibromocarbene or bromofluorocarbene addition to substituted allyldisilanes afforded instable gem-dibromocyclopropanes or a gem-bromofluorocyclopropane, respectively. These gem-bromohalogenocyclopropanes undergo a spontaneous ring opening at room temperature to give halogenated dienylsilanes or bromo dienes or dibromotetraenes.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry