Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5276032 | Tetrahedron Letters | 2011 | 4 Pages |
Abstract
The dibromocarbene or bromofluorocarbene addition to substituted allyldisilanes afforded instable gem-dibromocyclopropanes or a gem-bromofluorocyclopropane, respectively. These gem-bromohalogenocyclopropanes undergo a spontaneous ring opening at room temperature to give halogenated dienylsilanes or bromo dienes or dibromotetraenes.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry