Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5276038 | Tetrahedron Letters | 2011 | 4 Pages |
Abstract
A facile synthesis of novel Ï-conjugated 2,5-di(selenophen-2-yl)pyrroles (SeNSe) and 2,5-difuranylpyrroles (ONO) via Paal-Knorr reaction as the key step is presented. Photophysical and electrochemical studies of the various products have been explored. A bathochromic shift of the emission maximum is observed for all SeNSes over ONOs. Extended conjugation with a phenyl moiety further promotes the bathochromic shift. These SeNSe and ONO derivatives exhibit lower oxidation potentials than their terselenophene and terthiophene analogues.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Pitchamuthu Amaladass, Kalyan Kumar Pasunooti, Zihuan Png, Xue-Wei Liu,