Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5276103 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
When a good leaving group is present in the heteroaromatic azadiene, reaction with 2-aminopyrroles occurs by substitution by addition-elimination instead of cycloaddition. This novel reaction is sensitive to steric effects and takes place in 2-amino-1-methylpyrrole at C-5 and the exo amino group but at C-3 in 2-amino-1-t-butylpyrrole.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Michael De Rosa, David Arnold, Miroslav Medved',