Article ID Journal Published Year Pages File Type
5276359 Tetrahedron Letters 2007 5 Pages PDF
Abstract

Pd/Cu-catalyzed one-pot reaction of 1-trimethylsilyl-2-arylalkynes with propargylic chlorides in the presence of TBAF is described. The present new procedure is applicable to a wide range of silylated arylalkynes with both electron-withdrawing and electron-donating substituents. Functionalized allenynes can thus be obtained in good yields without prior deprotection of the alkynes.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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