Article ID Journal Published Year Pages File Type
5276545 Tetrahedron Letters 2007 4 Pages PDF
Abstract

Synthetic methodology to prepare porphyrinylethynyl enediynes has been developed. Compared to phenylethynyl derivatives, a bulky porphyrinic substituent on the alkyne significantly increases the thermal barrier toward Bergman cyclization and leads to multiple photolysis products.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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