Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5276575 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
The first α- and β-chiral water-soluble trialkylmonophosphines, 1 and 2, respectively, both with C3 symmetry, were synthesised from sodium phosphide and chiral mesylates, accessible from (S)-ethyl lactate. X-ray structures of a corresponding 2:1 gold(I) complex [12Au(I)]OTf and of a borane complex 2·BH3 were determined.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry