| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5276635 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
Gold-catalyzed reaction of 1-(3-hydroxypropynyl)cycloalkanol derivatives was studied. The reaction profile was highly dependent on the ring size, migrating group, as well as reaction conditions. An efficient route to spirocyclic furans via tandem [3,3]-sigmatropic rearrangement-cycloisomerization is reported.
Graphical abstractGold-catalyzed reaction of 1-(3-hydroxypropynyl)cycloalkanol derivatives was studied. The reaction profile was highly dependent on the ring size, migrating group, as well as reaction conditions. An efficient route to spirocyclic furans via tandem [3,3]-sigmatropic rearrangement-cycloisomerization is reported.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
![Au(I)-catalyzed tandem [3,3]-sigmatropic rearrangement-cycloisomerization cascade as a route to spirocyclic furans](/preview/png/5276635.png "First Page Preview: Au(I)-catalyzed tandem [3,3]-sigmatropic rearrangement-cycloisomerization cascade as a route to spirocyclic furans")
Authors
Hyun-Suk Yeom, Suk-Jae Yoon, Seunghoon Shin,