Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5276643 | Tetrahedron Letters | 2007 | 5 Pages |
Abstract
The enantioselective preparation of the tricyclo[4.4.0.05,7]dec-2-ene derivatives via the catalytic asymmetric intramolecular cyclopropanation (CAIMCP) reactions of α-diazo-β-keto esters with excellent ee (95–98% ee) is described. The chiral building blocks reported herein would be versatile intermediates for enantioselective natural products synthesis.
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