Article ID Journal Published Year Pages File Type
5276687 Tetrahedron Letters 2011 5 Pages PDF
Abstract
A new type of ring-ring isomerism, which consists of the reversible transformation of cyclobutane derivatives into substituted 1,2-oxazine N-oxides was found and studied by NMR spectroscopy and X-ray diffraction analysis. The starting materials were prepared by the stereoselective reaction of α-(trifluoroethylidene)nitroalkanes, which react with ethyl β-morpholino- and β-piperidinocrotonates at the more nucleophilic α-position, whereas the reaction of α-(trichloroethylidene)nitroalkanes proceeds at the β-methyl group to give the corresponding linear products.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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