Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5276819 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
Fischer carbene complexes having long alkynyloxy chains regioselectively produced oxametacyclophanes via the intramolecular Dötz reaction. The utility of this reaction was demonstrated in the synthesis of arnebinol, an ansa-type terpenoid, from geranyl acetate in six steps.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Masahito Watanabe, Kyosuke Tanaka, Yoko Saikawa, Masaya Nakata,