Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5276841 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
Chiral Co(salen) complexes bearing the Lewis acid of group 13 can efficiently catalyze the reactions of carbon dioxide with epoxides in the presence of catalytic amounts of alkali metal salts, quaternary ammonium halide or ionic liquids. They exhibited excellent activity for producing enantiomerically enriched cyclic carbonates.
Graphical abstractChiral salen (Co) complexes bearing the Lewis acid of group 13 can efficiently catalyze the reactions of carbon dioxide with epoxides in the presence of catalytic amounts of alkali metal salts, quaternary ammonium halide or ionic liquids. They exhibited excellent activity for producing enantiomerically enriched cyclic carbonates.Download full-size image
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Shu-Wei Chen, Rahul B. Kawthekar, Geon-Joong Kim,