Article ID Journal Published Year Pages File Type
5276994 Tetrahedron Letters 2010 4 Pages PDF
Abstract

Armed/disarmed effect of propargyl glycosides in the presence of AuBr3 is studied. Observed that oxophilic AuBr3 cleaves interglycosidic bond of an armed disaccharide resulting in the formation of a disaccharide and a 1,6-anhydro sugar. Trisaccharides were obtained after fine tuning the reactivity of the glycosyl donor with different protecting groups.

Graphical abstractDownload full-size image

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Authors
, ,