| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5277054 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
Iron tetrasulfophthalocyanine was immobilized on silica (FePcS-SiO2) and its activity examined on the allylic oxidation of cyclohexene using TBHP as oxidant. Under our reaction conditions, attack of the activated C-H bond was preferred instead of the epoxidation of CC bond, yielding 2-cyclohexen-1-one as the main product. μ-Oxo dimeric (d-FePcS) appears to be the active species for this reaction.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Lina M. González, AÃda L. Villa de P., Consuelo Montes de C., Alexander Sorokin,