Article ID Journal Published Year Pages File Type
5277141 Tetrahedron Letters 2008 4 Pages PDF
Abstract

The highly unsaturated aldehyde (9Z)-9,13-tetradecadien-11-ynal and the corresponding alcohol were identified as possible sex pheromone components of the avocado seed moth, Stenoma catenifer. The aldehyde as a single component attracted more male moths than caged virgin female moths, and addition of the analogous alcohol and/or acetate decreased attraction. A stereospecific synthesis of the pheromone is described.

Graphical abstractThe terminal dienyne of the title compound constitutes the first example of a new class of lepidopteran pheromone structures.Download full-size image

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Physical Sciences and Engineering Chemistry Organic Chemistry
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