Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5277506 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
A new and mild method was developed for the chemoselective conversion of mono-, bis- and tris-aminosiloxanes into their corresponding mono-, bis- and tris-dithiocarbamates, using alkaline hydrides and carbon disulfide in THF. Enhanced scavenging capacity towards mercury ions was observed when these compounds were grafted on silica compared to amine-functionalized silicas or to commercial resins bearing dithiocarbamate moieties.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Stéphanie Goubert-Renaudin, Raphaël Schneider, Alain Walcarius,