Article ID Journal Published Year Pages File Type
5277506 Tetrahedron Letters 2007 4 Pages PDF
Abstract

A new and mild method was developed for the chemoselective conversion of mono-, bis- and tris-aminosiloxanes into their corresponding mono-, bis- and tris-dithiocarbamates, using alkaline hydrides and carbon disulfide in THF. Enhanced scavenging capacity towards mercury ions was observed when these compounds were grafted on silica compared to amine-functionalized silicas or to commercial resins bearing dithiocarbamate moieties.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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