Article ID Journal Published Year Pages File Type
5277598 Tetrahedron Letters 2008 5 Pages PDF
Abstract

Various 2-alkylidenethietanes were synthesized by intramolecular nucleophilic substitution reactions at an sp2 carbon of vinyl halides with thiolate moieties. The reaction pathway of the substitution reactions was confirmed as a very rare SNVπ mechanism by theoretical and experimental studies.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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