| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5277677 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
Treatment of cis-4,5-diaminocyclohexene derivatives bearing allyl or propargyl groups on the nitrogen atoms, with first or second generation Grubbs metathesis catalysts, results in initiation of metathesis cascades which include ring-opening of the unstrained cyclohexene ring. This contrasts with the previous work on the analogous cyclohexene ethers where metathesis reactions occurred exclusively between the side-chains and no ring-opening of the cyclohexene unit was observed.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Elisabetta Groaz, Donatella Banti, Michael North,