| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5277697 | Tetrahedron Letters | 2017 | 4 Pages |
Abstract
The synthesis and structural characterization of a new hexahelicene derivative 2 is reported. This compound features a new type of structure bearing a bromine atom and a methoxy group. Suitable crystals of the latter indicate that its conformation closely resembles that of the unsubstituted [6]helicene, whose idealized symmetry is C2. This 3-bromo-14-methoxyhexahelicene was subjected to lithiation/phosphinilation and yielded the new 3-methoxy-14-(diphenylphosphino)hexahelicene 3.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
