Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5277904 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
We synthesized an artificial redox-active and Clâ-selective Fe-pseudocryptand as an anion receptor to respond to electrochemical oxidation and reduction. As the positive charge of the Fe center increases, the anion affinity effectively increased due to an enhanced electrostatic interaction between the Fe atom and the anionic guest.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Tatsuya Nabeshima, Sayuri Masubuchi, Norie Taguchi, Shigehisa Akine, Toshiyuki Saiki, Soichi Sato,