| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5277917 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
Reaction of enantiopure epoxides (1) with NO occurred highly stereoselectively, affording syn-ring opened products, nitrates (2). The configuration of 2 was confirmed to be retained by determining the configuration of reduced products 1,2-glycols (4) from 2. A possible mechanism is suggested to trace out the syn-ring opening pathway.
Graphical abstractReaction of enantiopure epoxides (1) with NO afforded syn-ring opened products, nitrates (2). Their configurations were confirmed to be retained by determining the configuration of reduced products 1,2-glycols from 2.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Wentao Wu, Qiang Liu, Yinglin Shen, Rui Li, Longmin Wu,