| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5278135 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
Oxidation of alcohols to aldehydes and ketones has been studied using atmospheric oxygen and a catalytic amount of Na6.3Fe0.9[AlMo11O39]·2H2O in toluene under heating (80 or 110 °C) in high yields. Secondary alcohols can be chemoselectively converted into ketones in the presence of primary hydroxyl groups.
Graphical abstractKeggin-polyoxymetalate complex Na6.3Fe0.9[AlMo11O39]·2H2O was demonstrated to be an effective solid catalyst for the selective oxidation of alcohols in the presence of air as oxidant.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Jianmin Wang, Liang Yan, Guang Qian, Xiaolai Wang,