Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5278196 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
A novel rearrangement of N-hydroxy indole derivatives obtained from addition of N-hydroxy indoles to the activated triple bonds of alkynes was found to coexist with 3,3-sigmatropic rearrangements to the indolic ring. A mechanism involving an intermediate oxaziridinium ring rationalizes the transformation.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Mariana P. Duarte, Ricardo F. Mendonça, Sundaresan Prabhakar, Ana M. Lobo,