Article ID Journal Published Year Pages File Type
5278282 Tetrahedron Letters 2009 4 Pages PDF
Abstract

A concise synthesis of the polycycle 27, which incorporates the 5,5,7-tricyclic ring core of rameswaralide 1, using a biogenetically inspired acid-catalysed [4+3]-cycloaddition approach starting from the furanobutenolide 26 is described, namely, 26→28/29→27. Under thermal conditions, the same furanobutenolide 26 gives the alternative polycyclic compound 35, resulting from a [4+2]-cycloaddition involving the furan as dienophile.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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