Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5278313 | Tetrahedron Letters | 2011 | 4 Pages |
Abstract
Tagged and activated d-glucose was introduced as a building block for branched oligosaccharides. This building block was the oligosaccharide branching point at which selectively the C-2 followed by the C-3 position can be glycosylated. After the activation of the C-1 position by oxidation of a thiophenyl group, the newly formed tagged oligosaccharide can be used as a glycoside donor. Synthetic procedures for the preparation of phthalimide-based tag molecules as well as tagged monosaccharides are presented.
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Authors
Sunil K. Upadhyay, Branko S. Jursic,