Article ID Journal Published Year Pages File Type
5278466 Tetrahedron Letters 2008 6 Pages PDF
Abstract

Nickel nanoparticles are prepared in the interlamellar spaces of K10-Montmorillonite clay by chemical reduction at moderate temperatures. These clay entrapped nickel nanoparticles are characterized by UV-vis, powder XRD, EDX and HRTEM studies. The resultant ecofriendly supramolecular assembly with nickel content (2.84 wt %) has good catalytic efficiency in hydrogenation of alkenes and alkynes with hydrazine as a reducing agent in ethanol medium. Advantages of the present study include absence of an external hydrogen source, catalyst reusability and a green medium.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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