Article ID Journal Published Year Pages File Type
5278503 Tetrahedron Letters 2009 4 Pages PDF
Abstract

The synthesis of a stable ketene aminal phosphate (α-phosphoryloxy enecarbamate) derived from N,N-diprotected acetamide, bearing two different removable protecting groups, is disclosed. This synthetic intermediate underwent successful palladium-catalyzed cross-coupling reactions to afford functionalized enynes and dienes.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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Acyclic ketene aminal phosphates derived from N,N-diprotected acetamides: stability and cross-couplings
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