| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5278519 | Tetrahedron Letters | 2009 | 5 Pages |
Abstract
Carbohydrate-derived cyclic nitrones were deoxygenated to form the corresponding imines using tributylphosphine. Experimental and theoretical investigations by the way of MP2 calculations suggest a revision of the mechanism initially proposed by Kurtzweil and Beak for the triarylphosphine-mediated deoxygenation of nitrones.
Graphical abstractCarbohydrate-derived cyclic nitrones were deoxygenated to form the corresponding imines using tributylphosphine. Experimental and theoretical investigations by the way of MP2 calculations suggest a revision of the mechanism initially proposed by Kurtzweil and Beak for the triarylphosphine-mediated deoxygenation of nitrones.Download full-size image
Related Topics
Physical Sciences and Engineering
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Authors
Pascale Cividino, Marie-Louise Dheu-Andries, Jun Ou, Anne Milet, Sandrine Py, Patrick H. Toy,