| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5278608 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
Epoxidation of the trisilyl-protected carbazomadurins A and B with dimethyldioxirane followed by desilylation provides a simple route to racemic epocarbazolin A and a non-diastereoselective access to epocarbazolin B. The Shi epoxidation has been applied to an asymmetric synthesis of the non-natural (â)-epocarbazolin A.
Graphical abstractEpoxidation of the trisilyl-protected carbazomadurins A and B with dimethyldioxirane followed by desilylation provides racemic epocarbazolin A and epocarbazolin B. The Shi epoxidation has been applied to an asymmetric synthesis of (â)-epocarbazolin A.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Jan Knöll, Hans-Joachim Knölker,