| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5278617 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
Anomeric carbon-sulfur bonds in 1-thioglycosides and glycosyl sulfones can be cleaved by chromium(II) complexes in water-DMF medium. Anomeric radicals as well as sugar-chromium(III) complex intermediates can be generated in these reactions, leading in some cases, to the exclusive formation of the corresponding glycals.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Károly Micskei, Zsuzsa Juhász, Zoran R. RatkoviÄ, László Somsák,