Article ID Journal Published Year Pages File Type
5278636 Tetrahedron Letters 2005 5 Pages PDF
Abstract

A rapid convergent synthesis of first- and second-generation halogenated linear poly(arylpropargyl ether) branches 7 and 10 is described. The key step of the sequence studied involves a selective Sonogashira-Linstrumelle (S-L) cross-coupling reaction of aryl iodides with alkynes bearing an sp2-carbon-iodine bond. Application to the synthesis of functionalized first-generation poly(arylpropargylether) stars having a benzene-1,3,5-tricarboxylic acid core has been realized.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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