Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5278636 | Tetrahedron Letters | 2005 | 5 Pages |
Abstract
A rapid convergent synthesis of first- and second-generation halogenated linear poly(arylpropargyl ether) branches 7 and 10 is described. The key step of the sequence studied involves a selective Sonogashira-Linstrumelle (S-L) cross-coupling reaction of aryl iodides with alkynes bearing an sp2-carbon-iodine bond. Application to the synthesis of functionalized first-generation poly(arylpropargylether) stars having a benzene-1,3,5-tricarboxylic acid core has been realized.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Nathalie L'Hermite, Jean-François Peyrat, Mouâd Alami, Jean-Daniel Brion,