| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5278667 | Tetrahedron Letters | 2011 | 4 Pages |
Abstract
Attempts to selectively arylate [6,6]-spiroacetal enol ethers at the 2-position delivered unexpected results. Palladium-mediated arylation conditions afforded the double-Heck product, whereas reaction with benzenesulfinic acid resulted in a facile rearrangement into the corresponding 5-phenylsulfonyl-3,4,5,6-tetrahydrochromans, providing access to 5-aryl-3,4,5,6-tetrahydrochroman and hexahydrochroman derivatives.
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Related Topics
Physical Sciences and Engineering
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Organic Chemistry
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