Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5278671 | Tetrahedron Letters | 2011 | 4 Pages |
Abstract
An efficient and high-yielding (up to 57% overall yield) asymmetric route to enantiopure P-stereogenic 1,2-bis[(o-hydroxyaryl)(phenyl)phosphino-P-borane]ethanes wherein aryl = phenyl and naphthyl, is presented. The occurring P-stereomutation is confirmed through X-ray crystal structure analysis of key intermediates.
Related Topics
Physical Sciences and Engineering
Chemistry
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Authors
Michel Stephan, Barbara Modec, Barbara Mohar,