Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5278724 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
The synthesis and utility of the novel axially chiral bis-urea ligand BINUREA are described. A complex of this urea ligand with ytterbium triflate and DBU can be used in the catalytic enantioselective Diels-Alder reaction of Danishefsky-type diene and electron-deficient olefins to give the adducts in good to excellent yield and enantiomeric excess (ee).
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Shinji Harada, Nozomi Toudou, Shiharu Hiraoka, Atsushi Nishida,