| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5278752 | Tetrahedron Letters | 2008 | 5 Pages |
Abstract
Presence or absence of electron-accepting dye chromophores is the key function for ON/OFF switching of fluorescence from the dihydrodibenzo[c,g]phenanthrene skeleton in 22+/3. The helical fluorophore in 22+ could be generated stereoselectively upon electrolysis of binaphthylic donor 1 through intramolecular chirality transmission. Huge chiroptical signals are easily detected by circular dichroism (CD) and fluorescence-detected CD (FDCD) techniques to realize novel four-way-output response.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
![Four-way-output molecular response system based on the dihydrodibenzo[c,g]phenanthrene skeleton: modulation of CD and FDCD activity by acid and electron-transfer](/preview/png/5278752.png "First Page Preview: Four-way-output molecular response system based on the dihydrodibenzo[c,g]phenanthrene skeleton: modulation of CD and FDCD activity by acid and electron-transfer")
Authors
Eisuke Ohta, Tatsuo Nehira, Hidetoshi Kawai, Kenshu Fujiwara, Takanori Suzuki,