Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5278812 | Tetrahedron Letters | 2006 | 5 Pages |
Abstract
Homologous biphenyl and (diastereomeric) binaphthyl tertiary azepines and quaternary iminium salts were prepared from (+)-(S,S)-l-acetonamine. Both the amines and iminium ions behave as effective catalysts for the enantioselective epoxidation of unfunctionalized olefins (ee up to 83%).
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Maria-Héléna Gonçalves, Alexandre Martinez, Stéphane Grass, Philip C. Bulman Page, Jérôme Lacour,