Article ID Journal Published Year Pages File Type
5278934 Tetrahedron Letters 2007 4 Pages PDF
Abstract

Enantioselective hydrosilylation of N-aryl and N-benzyl ketimines with trichlorosilane catalyzed by readily accessible chiral N-picolinoylaminoalcohols proceeded smoothly furnishing chiral secondary amines in good yields (up to 93%) and moderate to excellent enantioselectivities (up to 95% ee).

Graphical abstractEnantioselective hydrosilylation of N-aryl and N-benzyl ketimines with trichlorosilane catalyzed by readily accessible chiral N-picolinoylaminoalcohols proceeded smoothly furnishing chiral secondary amines in good yields (up to 93%) and moderate to excellent enantioselectivities (up to 95% ee).Download full-size image

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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