| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5279424 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
We have developed various transition metal-catalyzed vinylcarbene transfer reactions, such as ring-opening, substitution, and cyclopropanation reactions, using O-propargyl thiocarbamates as carbene precursors. Platinum, ruthenium, rhodium, and gold complexes are effective for vinylcarbenoid formation. The highly nucleophilic nature and resonance effect of a thiocarbamoyl moiety readily permit the rearrangement of a thiocarbamoyl moiety from a propargylic position to an adjacent alkynyl carbon to give the intermediary vinylcarbene complexes.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yuji Ikeda, Masahito Murai, Tomohiro Abo, Koji Miki, Kouichi Ohe,