| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5279425 | Tetrahedron Letters | 2007 | 5 Pages |
Abstract
Nickel complex catalysts, Ni(cod)2-2PPh3 and Ni(cod)2-dppb systems in particular, catalyze the addition reactions of phenyl allyl selenide to terminal alkynes to regioselectively afford 2-phenylseleno-1-allyl-1-alkenes in good to excellent yields. A mechanism that involves a η3-allyl–nickel complex is proposed on the basis of isolation, crystal structure determination and reactivity study of the complex.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
