Article ID Journal Published Year Pages File Type
5279441 Tetrahedron Letters 2007 5 Pages PDF
Abstract
The total synthesis of 15-membered peptide alkaloids abyssenine B and mucronine E was accomplished via olefination of phenylalanine-embodied aldehydes followed by CuI/N,N-dimethylglycine-catalyzed coupling of vinyl iodides with amides and FDPP-mediated macrocyclization in the key steps. From the total synthesis the stereochemistry of these two natural products was tentatively assigned to be S,S,S.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Authors
, , , ,