| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5279467 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
Reaction of macrocyclic diazocarbonyl compounds and alcohols or diols in the presence of rhodium(II) acetate catalyst led to functionalized macrocyclic di- or tetralactones via O-H insertion. Interestingly, the double O-H insertion reaction with dihydroxy compounds gave cryptands of various ring sizes.
Graphical abstractReaction of macrocyclic diazocarbonyl compounds with alcohols or diols in the presence of rhodium(II) acetate catalyst led to functionalized macrocyclic di- or tetralactones via O-H insertion. Interestingly, the double O-H insertion reaction with dihydroxy compounds gave cryptands of various ring sizes.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
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Authors
Sengodagounder Muthusamy, Boopathy Gnanaprakasam,