| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5279558 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
1-Hydroxyphosphonate 1 in the presence of triethylamine in acetonitrile solution undergoes irreversible rearrangement to phosphate 2 and reversible retro-phospho-aldol (retro-Abramov) reaction. The X-ray structures for 1 and 2 revealed that the phosphonate–phosphate rearrangement occurs with retention of configuration at the phosphorus atom.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
