| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5279578 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
Reactions of 1,4-dilithiobutadiene 5 with MeI in THF gave predominantly methyl iododiene 6. Monolithio monoiodo intermediate 8 was shown not to be involved in the formation of 6, but the results were consistent with the involvement of monolithio monomethyl intermediate 11, which could lead to 6 by metal-halogen exchange. Several other lithioalkenes also reacted with MeI to give alkenyl iodides.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Paul F. Hudrlik, Donghua Dai, Anne M. Hudrlik,