| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5279589 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
B(C6F5)3 as a catalyst and polymethylhydrosiloxane as a hydride source have been employed for the reductive dehydroxylation of Baylis-Hillman adducts wherein the hydride adds in an SN2â² manner onto the unactivated allyl alcohol moiety with concomitant elimination of the hydroxy group along with double bond migration. The products formed were found to be E in the case of ester adducts and Z in the case of nitrile adducts.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
S. Chandrasekhar, G. Chandrashekar, K. Vijeender, M. Srinivasa Reddy,