Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5279686 | Tetrahedron Letters | 2005 | 4 Pages |
Abstract
A new type of chiral Ru(II) complex, prepared from a conformationally rigid, sterically bulky 'roofed' cis-diamine and [RuCl2(benzene)]2, functions as an efficient catalyst for the asymmetric transfer hydrogenation of a wide variety of aryl ketones, including sterically bulky ketones, when the reaction is conducted in the presence of 5HCO2H·2NEt3.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hirofumi Matsunaga, Tadao Ishizuka, Takehisa Kunieda,