Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
52797 | Catalysis Communications | 2007 | 4 Pages |
Abstract
Salen complexes of iron(III) and manganese(III) were synthesized and employed as catalysts in the oxidation of cyclohexane, using hydrogen peroxide and tert–butylhydroperoxide. The reactions were carried out in acetonitrile at room temperature. The catalysts were characterized by infrared and Mössbauer spectroscopy, elemental analysis, conductivity and cyclic voltammetry. Conversions up to 10.2% (4.2% and 6.0% yields for cyclohexanol and cyclohexanone, respectively) were obtained for the system [Fe(III)(Salen)Cl]/tBuOOH.
Related Topics
Physical Sciences and Engineering
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Catalysis
Authors
Gisele C. Salomão, Mara H.N. Olsen, Valderes Drago, Christiane Fernandes, L. Cardozo Filho, O.A.C. Antunes,