| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5279840 | Tetrahedron Letters | 2005 | 4 Pages |
Abstract
Metalation-alkylation of 2-bromothiophene 1 when conducted at low temperature led to the 5-alkylated 2-bromo products 2. While, at room temperature, the same sequential reactions afforded the original dibromo-alkylated thiophenes 3 following an unprecedented halogen transfer-based halogen dance process in highly regiocontrolled and ordered way.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Corinne Peyron, Jean-Michel Navarre, Nathalie Van Craynest, Rachid Benhida,