| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5279884 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
A selective resin for linking trans-diequatorial-1,2-diols to solid support is described. This linking was carried out under mild and aprotic conditions involving the use of trimethylsilyl methyl ether in the presence of trimethylsilyl trifluoromethanesulfonate. Cleavage from the resin was also carried out under mild conditions by treatment with dichloromethane/trifluoroacetic acid/water (21:20:1). The usefulness of the described cyclohexane-1,2-diketone resin 7 in quinic acid chemistry was also studied.
Graphical abstractA selective resin for linking trans-diequatorial-1,2-diols to solid support is described.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Emilio Lence, Luis Castedo, Concepción González-Bello,