Article ID Journal Published Year Pages File Type
5280039 Tetrahedron Letters 2005 5 Pages PDF
Abstract
A frontier demarcating superelectrophilic compounds that undergo both Diels-Alder reactivity and σ-complexation reactions, from traditional electrophiles, is afforded through the thermodynamic tendency for σ-complexation as defined by the pKa values for H2O addition to electron-deficient aromatic and heteroaromatic substrates.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Preview
A criterion to demarcate the dual Diels-Alder and σ-complex behaviour of aromatic and heteroaromatic superelectrophiles
Authors
, , , , , ,