Article ID Journal Published Year Pages File Type
5280041 Tetrahedron Letters 2005 4 Pages PDF
Abstract

We report herein the reaction of 2,2-dibromomethylquinoxaline 2 with aromatic aldehydes 3a-g in the presence of TDAE. These reactions lead to a mixture of cis/trans-isomers of corresponding oxiranes 4a-g in good yields. The stereoselectivity of the reaction was sensitive to steric hindrance.

Graphical abstractWe report herein the reaction of 2,2-dibromomethylquinoxaline with aromatic aldehydes in the presence of TDAE. These reactions lead to a mixture of cis/trans-isomers of corresponding oxiranes.Download full-size image

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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