Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5280180 | Tetrahedron Letters | 2010 | 5 Pages |
Abstract
The pH of a solution shows a significant effect on the dynamics of the gate (formed by eight benzylic functions) and portal on the hydrophobic cavity of receptor. At pH 5.8 the gate closes and prohibits the entry of anionic guests. However, at pH 7.3 the gate opens and allows the entry of anionic guests into the hydrophobic cavity. It is the first time that anionic receptor efficiently recognizes anionic guests.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Satish Balasaheb Nimse, Keum-Soo Song, Junghoon Kim, Hyung-Sup Kim, Van-Thuan Nguyen, Woon-Young Eoum, Chan-Yong Jung, Van-Thao Ta, Taisun Kim,